POD 104: Paying the price for a free chemistry education
🕑 Added 2024-05-19 20:55:37 +0000 UTCA clandestine chemistry interview unlike any other I've done, this is the story of a man whose chemistry education was paid for by an organized crime ring. After learning the necessary skills, he was tasked with synthesizing increasingly large quantities of MDA under ever-rising pressure until the entire operation exploded.
Total Synthesis II
Secrets of Methamphetamine Manufacture
Notes on the synthesis of chloro/bromo/iodosafrole
Comments
Madelpine
Same
taylor gautreaux
I hope this guy gets to try 2cb
M
It seemed to be mainly in the 90s and early 2000s. Times have majorly changed
Brad
Damn this is legitimately a fucking crazy story. Thanks for this one Hammie
Joel
Hamilton, I've been following for over 5 years now. This is without a doubt one of the best, most unique stories you've brought to light. I've been on the edge of my seat listening through this over the past two days. Thank you for everything you do.
brady crow
Nothing that cool I was just omw to play music at a festival, got a ride from the WRONG dude and got busted w shrooms. Totally corrupt process the whole way. What IS interesting is the catalpa tree I discovered by my house the other day š I like keeping them a secret but this is a good place to ask what you know about them.
Hamilton Morris
Similar in that you were engaged in clandestine synthesis? If so, what were you making?
rabidreject
lol indeed, Iām now perusing your usernameā¦
rabidreject
I actually found the best RC fuel method yetā¦distill once with a column. Collect the 9% azeotropic mix of NM:MeOH in one container - this can be used AS IS in a Henry reaction, so far itās worked on 2,5-DMOBA and 3,4,5-TMOBA. I also then collect the fraction from 61c-101c in a separate container and either add water or saturated brine and boom it separates. Honestly, just using the azeotropic mix that I was using as glassware cleaner before was a revelation for meā¦š
brady crow
I have a similar story! I'm also from San Antonio and I host the best free shows in town if anyone wants to jam!
rabidreject
Hang onā¦.so you literally just add water and the nitromethane separates into a separate layer?! Iām literally grappling with this problem atm as my NM supplier disappeared and I already had 5l of that 30% red nitro fuel. I figured Iād do one distillation to rid it of oil and colour then a second fractional one to separateā¦well, the fractions I want! This sounds easier though! One thing I DO KNOWā¦.just adding it to a separate funnel and freezing it donāt do shit!
Kyle Langlois
Damn I didn't know about ther merck book ordered me one last night!
M
Dirty MDMA
Kevin O'Loughlin
The MDMA in Grand Cayman has been purple for at least the last 9 months.
Pyrrhus
So Austin/Texas gets mentioned multiple times as this semi hotspot for labs or psychedelics. But can't find any info
ansley b
where is this former mecca of clandestine botany?
giberic
Craziest fact I learned from this is that Hamilton has a skateboard
Corey Sauder
By š
rabidreject
Yeah I also laughed at that. White shirt and white jeans on a vertā¦.with a respirator for good luck š«£
M
Lol....
rabidreject
By the way, not sure that RC fuel separating in the fridge works for the red coloured stuff but if anything changes, Iāll update you guys.
rabidreject
Wow this guy put up with some SHIT. It seems like there are way more gangs waiting to expose people in your country than mine (depending on where you live really) - itās a sad state of affairs. I donāt think I would ever try classic things that are āwatchedā like that though - even if that wasnāt his personal issue. Something to be said for odd psychedelics in that respect I guess. Also not selling anything helps..haha I did have people asking me to make both MDMA and meth when I was in prison - I expect those were the gangs tbf!
rabidreject
Tbf, it was the second version of this book that actually got me interested and made me realise if I learned the actual terms of organic chemistry, I can at least follow Hamiltonās conversations a lot easier and then got interested in primary tryptaminesā¦but ultimately, it was a mixture of strikeās book and Hamiltonās first shown synthesis of n,n-DMT, that got me interested in organic chemistry. I mean, he taught me what reflux meant!
E up
love every side of this
Killion
Has Hamilton talked to Leonard about being on joe Rogan? Does Leonard want to?
Cheminterested
Right? I didn't know Hamilton skates. I'd love to see that
Cheminterested
I love how it just ends with Hamilton saying, "I have a skateboard."
defrank montana
Wow, his articulation of the timeline was very well put together. Great listen.
gossamer
Wow, what an incredible story. My heart broke listening to this one and Iām so glad he came out the other end okay and got to do only 9 months in prison. I hope heās doing well now and that life has been kinder to him since. Thank you so much for sharing his story. The skate ending was such a wonderful moment. <3
Mark Hertzler
Wheres the skate footage?! Epic end to that convoš¤ Gotta get you on a skate podcast nowā¦
Jameson kerr
Heās right about the even-numbered pages being missing from total synthesis 1. I went from incredibly elated to incredibly sad very quickly.
Kyle
Thumbs up on this one, looking forward to the skate edit
Crypto Tonight
I kinda wish you did outros. I always think my app crashed when the episode ends lol.
Crypto Tonight
This is a sobering cautionary tale for anyone who is thinking about getting involved in high level drug manufacture. I'm lucky that I didnt meet the wrong people back in my early 20's. This could so easily have been my life, I was stupid and naive and would have jumped at the opportunity to do chemistry.
M
I figured he had. It's too bad .
B-Boy Bungus
Multiple people have asked this question... He responded to another comment on this video about interviewing "Strike", he said: "I've tried, I'll try again."
M
Hamilton I'll write this again on the new episode but is there any chance of a Hobart Huson interview
Paul
I tried to distill a primary alkyl bromide, I stopped the stirring for 1 sec just to check how much product was still in the flask and it went from a pale yellow liquid to a deep red in less than a second. Of course each compound is different but it can definitely happen if you heat up too much. But you can't know until you try...
Tom
Can anyone let me know why there haven't been any questions and answers in awhile? Those are my favorites:(
Declan Mcqueeney
https://youtu.be/bij-89fpFBw?si=Lu8JCt6BpfNwjeTj
Declan Mcqueeney
Someone else may have commented this already, but there is an interview on youtube with a guy involved with distribution who was in competition with the mob guys who were forcing this man to work for them.
Nathan Stichter
The idea of donating books on lock picking and explosives to a high school had me dying lol
Nathan Stichter
Insane. His story would make quite a film
CSN
This dude was enslaved. Felt like that was left ambiguous. And he's definitely got some weird psychology lingering from it
B-Boy Bungus
Thanks for letting us know you've reached out. I figured you would have, but nice to have confirmation. I had a family member busted for a large amount of marijuana in 2000, and although he's the kind of person I would've expected to regale us with his adventures and tales, he really doesn't talk about it. Even with the subject of this interview "de-romanticizing" it, I think there are listeners that will romanticize regardless. My younger self would have tuned out the cautionary/troublesome aspects and focused on the things I wanted to hear.
Casper NorƩn
This is probably my new favourite episode and Iāve listened to just about all of them. Helps that it both sounds very realistic and is backed up but heās also really good at telling the story
Chad Barthalamew
holy shit
David Elsberry
Hamilton, that copy is missing the even numbered pages. Thatās what I was referring to, that the only copy on the internet that Iāve ever found was missing the even numbered pages. Sorry if I wasn't clear.
Hamilton Morris
I've tried, I'll try again.
Hamilton Morris
The first Total Synthesis is now linked in the description as well.
Tanner
Dudes got some balls telling his story . Respect
Gabe KS
Just when you thought the DEA couldnāt get any more cartoonishly ghoulish, that story about them trying to turn the mother of his children against himā¦unbelievable
Raleigh Smalls
But this guy's interview was so strong BECAUSE he de-romanticized it...and everyone knows the details of Strike's journey (if you know where to look) anyway, so...It's up to him. Even got Hamilton to get on a skateboard !
Kimberly shah
Such a unique perspective and what a gem to have come across. Thanks to him for sharing his story and to Hamilton for bringing it to us.
B-Boy Bungus
It's possible that Strike doesn't want to be interviewed. Some people that have been in legal situations are not as inclined to "glamorize" their previous behavior. Just because people on the internet think you are cool is not a great reason to go into details about past incriminating behavior. But I would love a Strike interview.
Raleigh Smalls
Why doesn't he have Strike on ?
David Elsberry
I misspoke, it is Total Synthesis, the first book, that I was referring to. The interview is amazing. I have read a lot about him, but this filled in so many gaps for me. Thank you!
Hamilton Morris
Total Synthesis II is linked in the description.
David Elsberry
This is one person that I thought I would never hear. Iād love to someday see the full copy of Total Synthesis II. Itās just not on the internet anywhere sadly and when a hard copy comes around itās quite expensive. Thank you Hamilton. If I could have picked anyone for you to interview, it would be him but I never thought he would tell his story. Absolutely fascinating.
Peter Thomas
Something about the way he talks reminds me of Frank Lyga.
Hamilton Morris
Despite the bias I mentioned, the reality is that I almost never encounter stories like this. Usually it really is law enforcement serving as the only antagonists.
Hamilton Morris
Yes, something is wrong. Yes, they meant helional at the start. The MAPS MDMA article repeats an error present in the original Schulze publication where the diagram mislabels heliotropin (aka piperonal) as helional. The additional carbons are coming from a Perkin reaction between piperonal, propionic anhydride, and sodium propionate.
Pvt. Idaho
All his advice is fantastic too
Pvt. Idaho
"We don't care about those people... They're not the ones we're after." š¤
Oscar Graham
I put this one on while having trouble falling to sleep. Ended up so engaged that I listed to the whole thing staying up till 4am⦠one of my favourite episodes, and Iāve listened to them all!
david
Sorry itās nagging me. Is something wrong with the 6th synthesis route in that MAPS mdma article? They say āCurtius Rearrangement from Helional (Schulze, 2010)ā but the first reagent is 2 carbons short of helional aka piperonal. So either it picks up 2 carbons from the Na ethanoate or from the prop anhydride. Or they meant helional at the start. Latter I think.
Enchanted FX
Iām glad youāre telling the darker side of things. As someone who moved to the former Mecca of clandestine botany I often come across stories like this. Its pretty universal that these types of folks want drugs to remain illegal or become more criminalized because there power to intimidate and blackmail is directly correlated to how illegal a substance is. The violence they use as a tool is super charged by the isolation cause by criminalization. So I think itās good to point out with these stories that repealing drug laws would do infinitely more harm to there business model than harsher sentences or higher law enforcement budgets which actually help them. I liked the phrase Hamilton used when he said, oh I thought you were just under medium pressure, because this is what I thought a lot , people are under medium pressure, but thatās not always the case. I do come across a lot of positive stories and still romanticize a lot too so I appreciate the full spectrum. Great Pod! Thanks to the Chemist for sharing, and Hamilton and Crew for all the good work! āļø
Phlegm
Hell yeah brother, skate or die! š¤š»
Douglas Skene
Amazing interview that felt super authentic and not trying to impress Hamilton. It's quite remarkable how much he spoke about the ins and outs of things giving a real sort of account of what it's like for some clandestine operators. I can only imagine the duress, danger and coercive tactics used to keep people manufacturing meth/amphetamine in my own country, and I somehow doubt the individuals would have received this educational scholarship. Fascinating.
Laura Ash
I understand your hesitancy to do interviews with people who have experienced violence/negative aspects of clandestine chemistry. However, I think Patreon is the best platform for this type of content, as the people here are here because they have an open mind about the ethics of these topics.. youtube is quite a different story. loved this one xx
Hamilton Morris
Though I find it odd that this phenomenon dosenāt seem well documented, I imagine these same issues would be far worse distilling something like t-butyl bromide where both products of the elimination are gasses
Hamilton Morris
But crucially you wouldnāt even need to break the vacuum manually. If the bromosafrole begins to eliminate at a sufficient rate it will effectively negate the vacuum via rapid pressure increase from gas evolution, likely self-promoting further elimination and pressure increase until the apparatus explodes.
david
TY!! That new reference is a good overview. In that document is referenced the start of distillation at 20 tor and 175C, so yep on the good vacuum you noted. I guess it's Boyle's law in effect when you break the vacuum. Delta T proportional delta P over the distillate which now can get way hotter before it vaporizes and I guess you get the entropic explosion. Wow.
Mike
Phenomenal interview. Thank you for taking the time to produce this material.
Hamilton Morris
He says that he was doing the distillation at 75ĀŗC, so he must have had an extremely good vacuum, obviously breaking the vacuum on a hot distillate can rapidly cause oxidative and thermal degradation, but I think this explosion could be caused without breaking the vacuum if the temperature is high enough to promote elimination.
Hamilton Morris
I also have spent some time trying to explain the explosion, which has been reported in slightly different terms by other chemists (I added a new reference to the episode description, search the word "volcano"). My first thought was simply that the E1/dehydrobromination reaction is exothermic, and that is likely part of what's going on, but more importantly the dehydrobromination is yielding a gas that could rapidly increase the pressure of the system at a rate that outpaces the vacuum. This is a back of the envelope calculation using the ideal gas law, but if you assume the distillation apparatus is a 200ml closed system containing 50ml of bromosafrole that spontaneously and quantitatively eliminates you would expect the pressure in the system to increase by twenty atmospheres, that should be more than enough to overwhelm the vacuum, blow the joints (i.e., explode), and depending on temperature and other factors rapidly cause a series of other reactions that create the "charcoal-decomposition-volcano" and "black smoke."
david
Can't post images but found this reference to a safrole bromination in the first image of the article, which is, by the way a pretty good one re the history of MDMA synthesis with the point being to show the MAPS 'novel' synthesis (for the purpose of patent). Would anyone care to comment on how this route compares to the route used by the chemist? https://unlimitedsciences.org/maps-brand-new-mdma-synthesis/ I'm still trying to understand what was causing his distillation 'explosion'. Was he releasing the vacuum to change the receiving flask? And am I correct in guessing that the best way to do this would have been a 'cow' receiving device or to have a stopcock somewhere in the system to isolate the changing of the flasks? Vacuum makes things bump or overflow worse it seems so what do you think was happening to cause what he called the 'uncoupling' when he released the vacuum which seems it might slow things down IMO? Was there a self sustaining thermal decomposition occurring as the vac was released?
Brett Egan
Hamilton throwing that heat latelyš„! So good!
Helmer
One of the best episodes yet, makes me think of Jesse in the last season of Breaking Bad.
Noel
Holy hell this was such a wild and interesting story!! I wish this guy the best
Phil Oad
Fantastic episode. A chilling and worthwhile cautionary tale. I especially appreciate your effort to use this particular podcast to provide a counterpoint to the oft-told 'clandestine chemistry is fun' narrative. Well done for admitting your own blind spots and please pass on our thanks to the interviewee.
Frost
thank you hamilton, I haven't come across something that spiked my curiosity like this patreon in far too long
reefer_rich123
As a avid skateboarder this oneās my favorite haha love the darker side of clandestine labs
Jeff gorski
Damn this oneās intense. Thank you so much for making my day with this interview.
B-Boy Bungus
Good work. Good questions, great story, plenty of details, chemistry forward with a twist of true crime... Maybe my favorite episode to date.
Tampasami
This was such a bountiful and fulfilling, inspiring listening experience. Thank you. Honestly I am full of gratitude to have been apart of this today. šš½
david
A tension tool and a rake, Some safrole and HBr to bake, Ammonia in a 30# tank Here is what ChatGPT with some help seems to think: In the heart of Texas, where cities sprawl, Lived a chemist clandestine, answering the call. His love for molecules, his passion untold, In the alchemy of atoms, his dreams unfold. With saffrole and HBr, he danced the dance, Mixing potions of hope, a risky chance. In the depths of his lab, where secrets reside, He crafted MDA with pride. College halls echoed with organic lore, Yet alone he was forced to delve to seek more. For his love of chemistry knew few bounds, In the symphony of reactions, his soul found. But shadows loomed over his humble abode, As organized crime cast its sinister code. Threats to family, chains of fear, Forcing his hand, he shed many a tear. Yet his heart remained true, a beacon of light, Amidst the darkness of a treacherous night. For he sought not wealth, nor power nor fame, But to heal with his craft, to ease human pain. In desperation, he sought the arms of law, To shield him from the crime's cruel claw. But the hands that should've offered grace, Revealed their own corrupted face. Bribes and threats, a twisted game, Yet he stood firm, unswayed by shame. For loyalty to his brethren, unwavering and strong, He would not betray, even when wronged. In the end, a soul torn by strife Seeking solace in the chaos of life. A chemist's tale, of love and despair, In the crucible of fate, he dared to care.
M
š
Ari Givony
This was one of your best podcasts Hamilton well worth the wait if you continue to release quality like this. Iāll have to listen to this again.
Raelyn Brewer
I second this.
KG - WC
Your such a beautiful soul Hamilton. Wanna go skate ! Loving.
SizTheWorld
What a great quotable š¤£
zealot
Love the ending! Quite a collection of MDxx episodes now !
Octopappa
Amazing!
Mason Sherman
š«”
Adam Perkins
I think it would be fascinating for you to do a two hour commentary dissecting everything discussed. That could be a podcast episode in itself. Really enjoyed hearing the making of a clandestine chemist starting with the early years. Hoping there are some backstories like this that will be incorporated in future interviews.
Cody
You wanna go skate?
Naked Suitcases
The ending was so sweet, he sounded so stoked to go skating š
Siwanand Das
Subscribed this month and good lord this is the best money I may have ever spent. Thank you Hamilton š
Tom J-L Harkness
š¤Æš
Kasey
(which isnāt discounting these stories and experiences btw, I just find it interesting how those things were in the water back then)
InterestChemist
Probably my favorite episode so far, great story and great story teller, knowledge wise only a couple of syntheses under my belt but wow I am captivated. The synthesis portion is always my favorite parts of stories like these. Thank you for letting him tell this amazing story!
Melbourne Lloyd Roth Jr
Loompanics rabbit hole, skateboard ending
Aidan
This is an amazing interview Hamilton, it's podcasts like these that blow my mind... an insane story that would never have been told if it weren't for you. ā¤ļø
Kasey
re lock picking and Uncle Fester, I first encountered Loompanics books at a shop literally called Spy Headquarters in Phoenix in around 1990. They sold everything from clandestine cameras to butterfly knives, it was an edgy little boyās dream. Chain books stores in the mid-90s were the nexus of all my clandestine interests - 2600 in the magazine rack at Barnes and Noble, finding Pihkal and Archaic Revival at Borders. The psychedelic hacker starter kit was literally on the shelf at the strip malls of the 90s.
Aidan
He liked his methamphetamine hot of the griddle? ššš
Paul
2hr+ clandestine chemistry podcasts will always be god tier. Thanks hamilton
Gabe Martinico
At first I thought to myself, id love the opportunity this man received and then I listened for a couple minutes. Thank you for sharing this story š
Hamilton Morris
Fixed.
Mason Sherman
Idk if itās just me but the links in the description donāt work
Riki Sharma
I'm elated, thank you!
Jason
Continuing the clandestine MDA synthesis saga. Thanks Hamilton!
Josip LediÄ
absolute banger I can already tell
M
First