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Chemistry - 1 Hour 42 Minutes

🕑 Added 2018-06-27 16:25:23 +0000 UTC

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Casey Goodman

Thanks for all the great videos!!

Michael Vander Velde

have you tried converting to moles

Tash Youdon

can someone solve this question for me plzzz

Tash Youdon

The solvent polarity has a substantial effect on the equilibrium between the two chair forms of trans-1,2-difluorocyclohexane. The following table quantifies the effect on solvent polarity on this equilibrium. Draw the chair form of each conformer with the axial-axial as reactant and equatorial-equatorial as product. Use Spartan (PM3) to calculate the dipole moment (this will be listed under “Display/properties”) for each. Explain why the eq-eq conformer is favored by solvents with a higher dielectric constant (e). J. Org. Chem. 2005, 70, 8381-8384. (Note: the solvent dielectric constant is proportional to its polarity) Compound E 13C data 22.59, 23.57, 52.66, 202.71 d Broadband decoupled DEPT-90 DEPT-135 (positive peaks) DEPT-135 (negative peaks) Solvent Methylcyclohexane di-n-butylether Tetrahydrofuran Acetone e K=eq/ax 2.0 4.4 3.1 7.6 7.6 29.8 20.7 51.3